The system catalogs are the place where a relational database management system stores schema metadata, such as information about tables and columns, and internal bookkeeping information. PostgreSQL's system catalogs are regular tables. You can drop and recreate the tables, add columns, insert and update values, and severely mess up your system that way. Normally, one should not change the system catalogs by hand, there are normally SQL commands to do that. (For example, CREATE DATABASE inserts a row into the pg_database catalog — and actually creates the database on disk.) There are some exceptions for particularly esoteric operations, but many of those have been made available as SQL commands over time, and so the need for direct manipulation of the system catalogs is ever decreasing.
If you see anything in the documentation that is not correct, does not match your experience with the particular feature or requires further clarification, please use this form to report a documentation issue.