LISTEN registers the current session as a listener on the notification channel named channel. If the current session is already registered as a listener for this notification channel, nothing is done.
Whenever the command NOTIFY channel is invoked, either by this session or another one connected to the same database, all the sessions currently listening on that notification channel are notified, and each will in turn notify its connected client application.
A session can be unregistered for a given notification channel with the UNLISTEN command. A session's listen registrations are automatically cleared when the session ends.
The method a client application must use to detect
  notification events depends on which PostgreSQL application programming interface
  it uses. With the libpq library,
  the application issues LISTEN as an
  ordinary SQL command, and then must periodically call the
  function PQnotifies to find out
  whether any notification events have been received. Other
  interfaces such as libpgtcl
  provide higher-level methods for handling notify events; indeed,
  with libpgtcl the application
  programmer should not even issue LISTEN
  or UNLISTEN directly. See the
  documentation for the interface you are using for more
  details.
NOTIFY contains a more extensive discussion of the use of LISTEN and NOTIFY.
LISTEN takes effect at transaction commit. If LISTEN or UNLISTEN is executed within a transaction that later rolls back, the set of notification channels being listened to is unchanged.
A transaction that has executed LISTEN cannot be prepared for two-phase commit.